Iron phosphide as negative electrode material for batteries
DOI: 10.1016/J.COCHE.2016.08.001 Corpus ID: 100303449; Polymer binder: a key component in negative electrodes for high-energy Na-ion batteries @article{Zhang2016PolymerBA, title={Polymer binder: a key component in negative electrodes for high-energy Na-ion batteries}, author={Wanjie Zhang and Mouad Dahbi … - Download [PDF]
Polymer binder: a key component in negative electrodes for high …
DOI: 10.1016/J CHE.2016.08.001 Corpus ID: 100303449; Polymer binder: a key component in negative electrodes for high-energy Na-ion batteries @article{Zhang2016PolymerBA, title={Polymer binder: a key component in negative electrodes for high-energy Na-ion batteries}, author={Wanjie Zhang and Mouad Dahbi …
PEDOT coated iron phosphide nanorod arrays as high …
Three-dimensional cobalt phosphide (CoP) nanowire arrays were synthesized on a carbon cloth and utilized as a binder-free supercapacitor negative electrode and shows high cycle stability with 82% capacitance retention after 5000 charge/discharge cycles, demonstrating that CoP is a promising negative electrode …
Polymer binder: a key component in negative electrodes for high …
In this article, we describe several main binding materials that have already been applied in the negative electrodes for Na cells, as shown in Figure 2.Poly(vinylidene fluoride) (PVdF) is a conventional binder for Li-ion batteries due to its good electrochemical stability and adhesion to the electrode materials and current collector.
Iron-cobalt phosphide/nitrogen-doped carbon composite …
Therefore, carbon and nitrogen-coated bimetallic phosphides of iron and cobalt (Fe 1-x Co x P/NC) are prepared as negative electrode materials for SIBs using a one-step phosphorization and carbonization method from MOF precursors. The material consists of CoP phosphorized from Fe Co Prussian blue analogs as the core, with …
Recent advances in electrospun electrode materials for sodium-ion batteries
Considering these advantages, electrospinning has been widely adopted to design high-performance electrode materials for Na-ion batteries in recent years. The following is a detailed discussion of the electrospun sodium-storage cathode and anode materials. ... iron nitrate/PVP/DMF: 350 °C for 2 h, 500 °C for 2 h, 900 °C for 4 h in O 2: …
Iron phosphide (FeP) synthesis, and full cell lithium-ion …
A scalable two-step strategy is utilized to synthesize iron phosphide (FeP) from iron oxide (Fe 2 O 3). The as-obtained iron phosphide is tested as a negative electrode for lithium-ion batteries …
Advanced flexible electrode materials and structural designs for …
As one of the essential components of a battery, electrode plays a vital role in determining the overall electrochemical performance and energy density. The conventional electrode is fabricated by slurry casting method, by which a mixture of active materials, conductive agents and polymer binders dissolved in organic solvent is coated …
(PDF) Electrodeposition of iron phosphide on copper substrate as ...
All samples are electrochemically tested as anode material against lithium between 0.01 and 2.5 V at constant 10 μAcm−2, rendering it as possible negative electrode for high energy density ...
Na,Electrochemistry …
FeP 2 FeP 4,Na。. FeP 2 Na。.,FeP 4 …
Nanostructured transition metal phosphide as negative electrode …
DOI: 10.1007/S11581-007-0170-3 Corpus ID: 97977840; Nanostructured transition metal phosphide as negative electrode for lithium-ion batteries @article{Boyanov2008NanostructuredTM, title={Nanostructured transition metal phosphide as negative electrode for lithium-ion batteries}, author={Simeon Boyanov …
Recent advances and perspective in metal coordination materials …
Abstract Recently, to ameliorate the forthcoming energy crisis, sustainable energy conversion and storage devices have been extensively investigated. Potassium-ion batteries (KIBs) have aroused widespread attention in these very active research applications due to their earth abundance and similar low redox potential compared to Li …
Vanadium diphosphide as a negative electrode material for sodium ...
Negative electrode materials with a large capacity and long cycle life are required for practical large‐scale sodium secondary batteries. Copper phosphide‐carbon composites containing various ...
Electrochemically induced amorphous-to-rock-salt phase ...
Intercalation-type metal oxides are promising negative electrode materials for safe rechargeable lithium-ion batteries due to the reduced risk of Li plating at low voltages. Nevertheless, their ...
Vanadium diphosphide as a negative electrode material for …
To investigate the electrochemical performance of VP 2, galvanostatic charge-discharge tests were performed on a half-cell configuration consisting a Na metal counter electrode and Na[FSA]–[C 3 C 1 pyrr][FSA] (20 : 80 in mol) ionic liquid IL in the voltage range of 0.005–2.0 V at temperatures of 25 and 90 °C as highlighted in Fig. …
Iron phosphide as negative electrode material for Na-ion batteries
Sn4 P3 is introduced for the first time as an anode material for Na-ion batteries and shows very stable cycle performance with negligible capa-city fading over …
Advances in metal phosphides for sodium-ion batteries
Zhang et al 61 synthesized FeP 4 materials by ball milling method using the phosphorus and iron powder as raw materials. When evaluated as negative electrode for SIBs, the obtained FeP 4 showed a large discharge capacity of 1137 mA h g –1 accompanied by 84% Coulombic efficiency during the first discharging-charging process at 89 mA g –1.
Evaluation of Metal Phosphide Nanocrystals as Anode Materials …
Sodium-ion batteries (SIBs) are potential low-cost alternatives to lithium-ion batteries (LIBs) because of the much greater natural abundance of sodium salts. However, developing high-performance electrode materials for SIBs is a challenging task, especially due to the ∼50% larger ionic radius of th …
Iron phosphide@N-doped carbon nanosheets with open …
Iron phosphide@N-doped carbon nanosheets with open-framework structure as an ultralong lifespan and outstanding rate performance electrode material for sodium-ion batteries Author links open overlay panel Zhaolin Li a, Hailei Zhao a b, Zhihong Du a b, Lina Zhao a, Jie Wang a b, Zijia Zhang a
Facile synthesis of hollow Cu 3 P for sodium-ion batteries anode …
Combining metal to form metal phosphide is a promising strategy to address the fast capacity decay of P rooted from its low electronic conductivity and large volume changes upon cycling. Cu3P, which possesses a high theoretical gravimetric and volumetric capacity of 363 mAh·g−1 and 1028 Ah·L−1 and reasonable volume expansion …
Negative electrodes for Na-ion batteries
This paper sheds light on negative electrode materials for Na-ion batteries: carbonaceous materials, oxides/phosphates (as sodium insertion materials), sodium alloy/compounds and so on. These electrode …
Recent Progress on Nanostructured Transition Metal Oxides As …
Lithium-ion batteries (LIBs) have been broadly utilized in the field of portable electric equipment because of their incredible energy density and long cycling life. In order to overcome the capacity and rate bottlenecks of commercial graphite and further enhance the electrochemical performance of LIBs, it is vital to develop new electrode materials. …
Cobalt-based electrode materials for sodium-ion batteries
As an anode material for SIBs, Co 3 O 4 goes through a conversion reaction during charge/discharge process [79], [80].As can be seen in Fig. 1 a, the structural evolution of this material has been investigated systematically by ex-situ TEM and selected area electron diffraction (SAED) at different charge/discharge states. In detail, upon the …
Iron phosphide as negative electrode material for Na-ion batteries
Iron phosphide as negative electrode material for Na-ion batteries by Zhang W, et al.. Electrochemical Communications. Read more related scholarly scientific articles and …
Phosphorus‐Based Composites as Anode Materials for …
Phosphorus-based materials including phosphorus anodes and metal phosphides with high theoretical capacity, natural abundance, and environmental friendliness show great potential as …
Advances in metal phosphides for sodium-ion batteries
Zhang et al 61 synthesized FeP 4 materials by ball milling method using the phosphorus and iron powder as raw materials. When evaluated as negative electrode for SIBs, the obtained FeP 4 showed a large …
Na,Electrochemistry …
FeP 2FeP 4,Na。FeP 2Na。,FeP 489 mA·g -11137 mAh·g -1,84.0％。 …
Vanadium diphosphides as negative electrodes for secondary Li-ion batteries
In contrast with the reported Fe-P alloy prepared using zerovalent iron and phosphorus as raw materials [2,3], the Fe 1.5 P alloy prepared using Ca 3 (PO 4 ) 2 and Fe 2 O 3 has better cycle and ...
Mechanism research progress on transition metal compound electrode …
MnO 2 is another classic PC material after RuO 2 and is a base metal oxide with good electrochemical performance in neutral environments (Na 2 SO 4 and K 2 SO 4).Notably, MnO 2 exhibits high theoretical capacitance (1390 F·g −1), cost-effectiveness, minimal toxicity and environmentally friendly attributes.Researchers have …
Preparation and Properties of Iron Phosphide Composites as …
The development of new lithium-ion battery anode materials with high specific capacitance and remarkable cycle stability is one of the key points in exploration of new energy materials. In this work, phytic acid was used as the phosphorus and carbon source, and the precursor containing phytic acid and cobalt was simply synthesized by precipitation …
Iron phosphide as negative electrode material for Na-ion …
Iron phosphide as negative electrode material for Na-ion batteries Wanjie Zhanga, Mouad Dahbia,b, Shota Amagasaa, Yasuhiro Yamadaa, Shinichi Komabaa,b,⁎ a Tokyo University of Science, Shinjuku, Tokyo 162-8601, Japan b Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, Kyoto 615-8245, Japan article info abstract …
Progress of metal phosphides as the anode materials for sodium …
Metal phosphide has been recognized as a promising anode material for sodium-ion batteries due to its high theoretical specific capacity and suitable redox potential.However, the challenges such as poor electronic conductivity and large volume expansion of metal phosphide lead to poor cyclic stability of metal phosphide, which …
Iron phosphide as negative electrode material for Na-ion batteries
Iron phosphides, FeP 2 and FeP 4, have been synthesized and characterized for the application to non-aqueous Na-ion battery.FeP 2 shows no significant electrochemical reactivity in Na-cell. However, FeP 4 composite electrode with sodium polyacrylate binder delivers a reversible capacity of 1137 mAh·g − 1 and a Coulombic efficiency of 84.0% …
Characteristics and electrochemical performances of silicon/carbon ...
We report the interfacial study of a silicon/carbon nanofiber/graphene composite as a potentially high-performance anode for rechargeable lithium-ion batteries (LIBs). Silicon nanoparticle (Si ...
Iron phosphide as negative electrode material for Na-ion batteries
Although the sodiation mechanism of FeP4 has not been fully understood, FeP4 is a new promising negative electrode material for Na-ion batteries with both …
Iron phosphide (FeP) synthesis, and full cell lithium-ion battery …
A scalable two-step strategy is utilized to synthesize iron phosphide (FeP) from iron oxide (Fe2O3). The as-obtained iron phosphide is tested as a negative electrode for lithium-ion batteries both in half cell and full cell configurations. The electrochemical performance vs. lithium exhibits a capacity retention of 53.7% of the …
Iron phosphide as negative electrode material for Na-ion …
In the recent developments for Na-ion batteries, negative electrode made of red phosphorus, which enables three-electron reversible redox with Na, has been reported to …
Advanced Anode Materials for Rechargeable Sodium-Ion Batteries
Rechargeable sodium-ion batteries (SIBs) have been considered as promising energy storage devices owing to the similar "rocking chair" working mechanism as lithium-ion batteries and abundant and low-cost sodium resource. However, the large ionic radius of the Na-ion (1.07 Å) brings a key scientific challenge, restricting the development …