Solar energy. Organic solar cells (OSCs) have been recognized to have tremendous potential as alternatives to their inorganic counterparts, with devices that are low-cost, lightweight, and easily … - Download [PDF]
Solar energy. Organic solar cells (OSCs) have been recognized to have tremendous potential as alternatives to their inorganic counterparts, with devices that are low-cost, lightweight, and easily …
In an efficient organic solar cell, almost all photo-generated spin-singlet excitons dissociate into free charges; photon emission occurs after free-charge …
The device efficiency of organic solar cells is usually limited by the inherent energy loss during carrier transport. Here, authors integrate bulk heterojunction organic photovoltaic with vertical ...
Since the discovery of high conductivity in perylene-iodine complex in 1954, organic semiconductors have been under intense research [].Potential applications of organic semiconductors emerged when Tang et al. demonstrated the first OLED in the 1970s [].With the unique properties of organic semiconductors of flexibility, thinness, and …
An organic solar cell device or organic photovoltaic cell (OPVC) is a class of solar cell that uses conductive organic polymers or small organic molecules for light absorption and charge transport. These devices are relatively easy to fabricate, can also be processed on flexible substrates, however they have relatively low conversion ...
Perovskite solar cells (PSCs) have been brought into sharp focus in the photovoltaic field due to their excellent performance in recent years. The power conversion efficiency (PCE) has reached to be 25.2% in state-of-the-art PSCs due to the outstanding intrinsic properties of perovskite materials as well as progressive optimization of each …
In this article, electron transporting layer (ETL) materials are designed to enhance the performance and stability of methyl ammonium lead iodide (MAPbI3) perovskite solar cells (PSCs). The optical and electronic properties of the designed ETLs are investigated using density functional theory. The designed ETLs show better charge …
In this work we propose a simple and fast characterization of electron-transfer processes to find the rate constants by analysing the distribution of vertical excitation energies of both …
Despite general agreement that the generation of free charges in organic solar cells is driven by an energetic offset, power conversion efficiencies have been improved using low-offset blends. In this work, we explore the interconnected roles that exciton diffusion and lifetime play in the charge generation process under various …
The exploitation of the solar energy, most typically the photovoltaic (PV) application, is a pivotal way to realize carbon neutrality 1.PV installation has been growing, and is expected to reach ...
Semi-transparent organic solar cells'' (ST-OSCs) photovoltaic and high optical performance parameters are evaluated in innovative applications such as power-generating windows for buildings ...
In this work, the interaction between an analogue of PBTZT-stat-BDTT-8, a high-performance D–A statistical copolymer developed by Merck, and phenyl-C 61 -butyric acid methyl ester is explored, with a focus on (i) the …
This contribution aims to provide an introductory review and comparison of the light-induced charge-transfer mechanisms occurring in natural photosynthesis and synthetic organic photovoltaics, with a …
Ultraclean transfer of CVD-grown graphene and its application to flexible organic photovoltaic cells† Cheng Jin An, a Seon Joon Kim, a Hyung Ouk Choi, a Dae Woo Kim, a Sung Woo Jang, a Ming Liang Jin, a …
In organic solar cells (OSCs), both charge generation and charge recombination occur at the donor (D)–acceptor (A) interfaces. Therefore, the energy level alignment (ELA) at D–A interfaces is ...
Impedance spectroscopy has been widely applied over the last decades to study electrochemical systems and solid-state devices. However, performing impedance spectroscopy on emerging photovoltaics presents new challenges related to the unusual material properties and complex device architectures. This review provides an …
Organic photovoltaics have achieved efficiencies near 11%, but efficiency limitations as well as long-term reliability remain significant barriers. Unlike most inorganic solar cells, OPV cells use molecular or polymeric …
In organic solar cells, the charge-transfer (CT) electronic states that form at the interface between the electron-donor (D) and …
The coupling transfer integral is estimated to be 12.7 meV ... Yuan, J. et al. Single-junction organic solar cell with over 15% efficiency using fused-ring acceptor with electron-deficient core.
Silicon . Silicon is, by far, the most common semiconductor material used in solar cells, representing approximately 95% of the modules sold today. It is also the second most abundant material on Earth (after oxygen) and the most common semiconductor used in computer chips. Crystalline silicon cells are made of silicon atoms connected to one …
Organic photovoltaics have achieved efficiencies near 11%, but efficiency limitations as well as long-term reliability remain significant barriers. Unlike most inorganic solar cells, OPV cells use molecular or polymeric absorbers, which results in a localized exciton.
Single-junction organic photovoltaic cell with 19% efficiency. ... Over 19.2% efficiency of organic solar cells enabled by precisely tuning the charge transfer state via donor alloy strategy. Adv. Sci., 9 (2022), Article 2203606, 10.1002/advs.202203606. View in Scopus Google Scholar [5]
In organic solar cells, the charge-transfer (CT) electronic states that form at the interface between the electron-donor (D) and electron-acceptor (A) materials have a crucial role in exciton ...
where (frac{e{{a}^{2}}}{hbar }) has the dimension of a carrier mobility, and is close to 1 cm 2 /Vs for most organic crystals.. It is also worth noting that at high field (> 10 5 V/cm), the carrier transport in organic materials is field-dependent. This is because the external field can alter the columbic potentials near localized-energy levels, thus …
Time of flight (TOF), space charge limited current (SCLC), charge extraction by linearly extracting voltage (CELIV), and impedance spectroscopy as the …
Organic compounds are mainly hydrocarbon compounds with a backbone of carbon atoms. The strong bonds that form the molecular backbone are a result of overlap of sp 2 hybridized atomic orbitals of adjacent carbon atoms, yielding a bonding σ and an antibonding σ* orbitals. The remaining unhybridized p orbitals overlap and form π …
Recently, organic solar cells have surpassed 17% 1,2 power conversion efficiency (PCE) in single-absorber layer bulk heterojunction (BHJ) devices based upon non-fullerene electron acceptor systems ...
Organic Photovoltaic Solar Cells. NREL has strong complementary research capabilities in organic photovoltaic (OPV) cells, transparent conducting oxides, combinatorial methods, molecular simulation methods, and atmospheric processing. ... Fundamental understanding of charge transfer between organic materials and novel excitonic …
where q is the elementary charge, εε 0 the dielectric permittivity, μ n the electron mobility and μ p the hole mobility. Although there are a number of systems in which k 2 is significantly reduced compared to Langevin recombination (k 2 = ζk L, where ζ < 1), the reduction is usually not great enough to ensure thickness-insensitive device …
The bulk morphology of the active layer of organic solar cells (OSCs) is known to be crucial to the device performance. The thin film device structure breaks the symmetry into the in-plane ...
For organic solar cells to be competitive, the light-absorbing molecules should simultaneously satisfy multiple key requirements, including weak-absorption charge transfer state, high dielectric ...